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instead, they appear to employ a hit-and-run (TheorellChance) mechanism in which acetyl (or lactyl) transfer occurs without a stable enzymesubstrate ternary complex [48]

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Meanwhile, in non-selenium containing Gpxs, which represent the majority of non-vertebrate Gpxs, the selenocysteine residue at the active site is replaced by a cysteine residue and the enzyme follows Michaelis Menten saturation kinetics (Toppo et al., 2009)

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